W/C RATIO LAW
The lower the
water-cement ratio, the higher is the strength of concrete, provided the mix is workable".
S = K {C/c+e+a}2
Where S = Strength
of concrete
K = constant
c = volume of cement
e =volume of water and
a = volume of air
Limitations of water
cement ratio law
1. The internal
moisture conditions of concrete specimens is uniform.
2. The concrete
specimens to be tested is cured under standard temperature.
3. The concrete
specimens to be tested is of same age.
4. The concrete
specimens to be tested is of same size.
The effects of these
conditions on strength of concrete are :
1. Effect of
internal moisture conditions on hydration of cement : The hydration of cement
continues so long as the capillary pores are filled with water. hence to
maintain the continuity of reaction the internal moisture condition should be
maintained for the important period of hydration. That means curing should be
done for 28 days.
2. Effect of temperature on hydration of cement :
At higher temperature the rate of reaction i.e. formation of gel is faster and
strength develops at a faster rate. This faster development of strength does
not cause full hydration of cement and hence produces poious concrete witless
ultimate strength. Indian standard has specified a curing temperature of 27 +
(-) 3o C for proper hydration of cement.
3. Effect of age on
concrete strength : Usually strength of concrete increases with age. Water
cement ratio law is applicable only when the strength of concretes at the same age
and compared. according to Indian Standard, 28 days strength of concrete has
been specified for comparison.
4. Effect of size of
specimen on strength of concrete : It has been found that for the same mix
proportations, smaller size specimen gives greater strength than the large size
specimen. Indian standard as specified a standard Cube size of 150mm side. if
used 100mm size cube then strength should
be reduced by 10% so as to get the strength of 150 mm size cube. Where cubes
larger than 150 mm size are used, generally no modification necessary unless
otherwise specified by engineer-in-charge.
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